You should activate the option: "Use compressed files from js/xenforo/" because that's where the compressed files are. They are not stored in js/xenforo/min/ and unless you're a XenForo developer, or you know what you're doing, you really shouldn't be changing anything here.
I'm not sure of the exact use case of that option, but I'm certain it has some relevance in terms of developing the core software, or it is a legacy setting.
Those options are hidden on a default installation and only shown when in debug mode. They aren't designed to be changed by end users without absolutely knowing what they are doing and usually only for development purposes.
If you see them, you are running your site in debug mode, which I can only suggest that you don't. Debug mode isn't meant to be used in a production environment.